Chapter 19: Chemicals used in Daily Life
Different types of chemicals are used in our daily life. Some are natural and some are manufactured in industries — for example chemicals used for cleaning, food preservatives, pesticides, chemicals used to preserve fruits and vegetables, and chemical fertilizers.
Industrial chemistry is the branch of chemistry in which we study the different aspects of transformation of matter to manufacture materials useful to mankind through chemical processes.
Common chemicals used in daily life: detergent, sugar, soap, salt, insecticide spray, and rat poison.
1. Food Preservatives
What are Food Preservatives?
Food gets decayed due to the growth of bacteria, yeast, and mold on it. Substances used to protect food from decaying are called food preservatives.
They are used to prevent food from decaying for a long time — cereals, legumes, vegetable products, fruits and vegetables, and animal products like meat, milk and milk products. Food preservatives check the growth of bacteria, yeast, and mold in food.
Very Important for SEE: Food preservatives are of three types — chemical food preservatives, natural food preservatives, and preservatives that induce ripening of fruits.
Classification of Preservatives
| Class | Source | Rule of use | Examples |
|---|---|---|---|
| First class preservatives | Natural sources | Can be used in necessary amounts | Sugar, salt, vinegar, honey, spices, edible oils |
| Second class preservatives | Obtained by chemical derivation of compounds | Can be used only in a certain/limited amount; not more than one type should be used in any food | Sodium/potassium nitrate, benzoic acid and its salts, sulphur dioxide |
1. Chemical Food Preservatives
Salt and oil control the growth of microscopic germs and organisms. Chemicals like sodium benzoate, sorbate, sulphur dioxide, nitrates and nitrites, butylated hydroxyanisole (BHA), butylated hydroxytoluene (BHT), calcium propionate, and sodium metabisulfite are also used as food preservatives.
Common chemical food preservatives (sodium benzoate, sorbate, propionates) and natural preservation methods (lemon juice, vinegar, salt curing, freezing).
2. Natural Food Preservatives
Natural food preservatives come from organic matter (plants, animals, fungi and algae) and prevent food materials from decaying. Examples: mugwort (Titepati), neem oil, lemon concentrate (Chuk).
Traditional natural methods of food preservation include drying in the sun, keeping in cold places or above water, use of wood ash, and mixing turmeric with oil. Modern methods include pasteurization, freezing, and keeping food in cold stores. All these methods control the conditions microbes need to grow.
3. Food Preservatives for Inducing Ripening of Fruits
Fruits like mango and banana take a long time to ripen even after maturation, so chemicals are used to induce fast ripening. These chemicals are called ripening agents. Examples: calcium carbide, ethylene gas, ethephon.
A chemical ripening agent (calcium carbide sachet) being used to ripen mangoes.
Traditional ripening methods include wrapping fruits in a jute sac, using Asuro (Malabar nut) leaves, keeping fruits in a pit covered with soil, or wrapping them in husk or hay.
SEE Focus: Calcium carbide is used excessively nowadays because it is cheap and easy, but overuse can cause skin irritation, skin burning, red blisters, lung effusion, and eye irritation. It should be used carefully and never in excess.
2. Chemicals Used in Cleansing
Natural Materials Used in Cleansing
Reetha (soapberry), Peena (mustard seed cake), wood ash, lemon juice, and Sajiban are natural materials used for cleansing purposes.
Natural materials used for cleansing: reetha (soapberry), peena (mustard seed cake), wood ash, and sajiban leaves.
Reetha (Soapberry)
Reetha contains saponin, which acts as a foaming agent, so it can be regarded as a soft natural soap. It has been used for centuries to clean the body and wash clothes, and is a traditional medicinal tree found in Nepal, India, and China. Its powdered fruit is used in shampoo as a foaming agent.
Peena (Mustard Seed Cake)
Peena has long been used in Nepal to wash hair and make it soft and strong. It contains nutrients important for healthy hair growth, such as folate, niacin, thymine, and vitamin B6 (forms of vitamin B complex). Its use can control hair fall and keep hair soft and healthy.
Wood Ash
Wood ash mixed with a little water forms a paste that works as an abrasive cleaner. It can brighten metals, clean dirty utensils, and remove sticky residue and adhesive. It is also a good source of potassium, phosphorus, and magnesium for plants, so it can be used as a fertilizer.
Sajiban
Sajiban (Jatropha curcas) is a useful plant found naturally in different regions of Nepal. Animals do not eat it, so it can be used as a fence. Its leaves make compost manure, its juice cures burns, it can be used as anticancer medicine, and its twigs are used for brushing teeth. It is a good source of nitrogen, phosphorus, and potash, so it is also used as an organic fertilizer.
- Sajiban's juice and oil can be applied on cattle to kill lice.
- Its oil cures skin diseases/infections and relieves muscular and joint pain.
- Its oil is used to make soap and to light lamps.
- Its oil can also be used to produce glycerin.
- Nepal's Sajiban seeds contain about 30–48% oil; about 1 litre of oil can be produced from 3 kg of Sajiban seeds, making it an excellent source of biodiesel.
Lemon Juice
Lemon juice contains citric acid in high concentration. It is a good natural cleaner due to its low pH value and antibacterial properties, and it also works as a natural bleach. It cleans without damaging wood or clothes, cleans copper surfaces efficiently, and has been used as a medicine for decades.
3. Chemicals Used in Cleansing
Soap
The sodium or potassium salts of long chain fatty acids are called soap. Animal fat or vegetable oil, sodium hydroxide, and sodium chloride are the raw materials for making soap.
The process of making soap by the hydrolysis of vegetable oil or animal fat with alkali is called saponification.
Diagram of the soap-making process: mixing oil with NaOH, heating, and separating soap crust from glycerol.
- Soap produces insoluble scum with hard water, so it is not an efficient cleaner in hard water.
- Soap is biodegradable, so it does not cause chemical pollution.
- In soap-making, the filtrate left after removing the soap crust contains glycerin.
Detergent
Detergent is a substance used to clean clothes. It is a chemical obtained from hydrocarbons that is more soluble in water than soap, so it is also known as soapless soap.
Detergent powder, a soapless synthetic cleaning agent used to wash clothes.
- It cleans clothes like soap, but its chemical nature is different from soap.
- It can be used with hard water as well.
- Examples: sodium lauryl sulphate, alkyl benzene sulphonate, sodium pyrophosphate.
- It is non-biodegradable (unlike soap), so it can cause chemical pollution.
- Long-term use can cause skin irritation or skin burns, soil and water pollution, and can fade the colour of clothes.
4. Chemical Pesticides
What is a Pesticide?
Poisonous substances used to remove, destroy, kill, and control harmful pests from seeds, plants, trees, birds, animals, human health, and construction areas are called pesticides.
According to the Pesticide Management Act 2076 (B.S.), 'pesticide' means any organic, vegetation, biological, or chemical material used to protect plants, agricultural products, forests, living beings, livestock, human health, storage, packaging, and construction works from harmful disease, insect, mite, nematode, weed grass, and rodents.
SEE Focus: DDT was first imported to Nepal in 1952 AD to control malaria. The average use of pesticides in Nepal is about 396 grams per hectare. About 80% of used pesticides get mixed into the soil and take a long time to diffuse, destroying soil microorganisms and risking pollution of surface and underground water.
Types of Pesticides
On the basis of effect on the environment, the pests they affect, and mode of action, pesticides are classified as follows.
(1) On the Basis of Effect on the Environment
| Type | Description | Example |
|---|---|---|
| Biodegradable / non-persistent | Break down into harmless compounds by microbes and other organisms within a short time on contact with water, air, light, or heat. | Dimethoate (Nugor, Rugor, Dimet), Malathion |
| Non-biodegradable / persistent | Do not decompose easily and remain in the food chain for a long time; banned in most countries including Nepal. | DDT, Aldrin |
(2) On the Basis of the Pests They Affect
| Type | Used against | Example |
|---|---|---|
| Insecticides | Harmful insects | Malathion, Cypermethrin, Fenvalerate, Nitenpyram |
| Fungicides | Fungi and fungal diseases | Dimethomorph, Sectin, Mancozeb, Carbendazim |
| Herbicides | Unwanted herbs/weeds | Butachlor, Isoproturon, Atrazine |
| Rodenticides | Rats and rodents (mice, squirrels, hamsters, porcupines) | Zinc phosphide, Bromadiolone, Coumatetralyl |
| Miticides | Mites | Bifenazate, Fenazaquin, Propargite, Fenpyroximate |
(3) On the Basis of Mode of Action
| Type | Mode of action | Example |
|---|---|---|
| Contact pesticides | Kill pests when their body directly touches the pesticide. | Malathion, Chlorpyrifos |
| Internal pesticides | Kill pests when they consume treated leaves, flowers, or fruits. | Malathion, Cypermethrin, Fenvalerate |
| Systemic pesticides | Absorbed by plant parts (roots, leaves), making the whole plant poisonous to insects that feed on it. | Thiamethoxam, Dinotefuran |
| Fumigant pesticides | Produce poisonous gas/fumes on contact with air; used mainly during storage of agricultural products. | Aluminium phosphide, Methyl bromide |
A farmer spraying chemical insecticide on crops in a field.
Safety Precautions in the Use and Storage of Pesticides
Safe storage of pesticides: a locked, labelled, ventilated pesticide storage cabinet with warning signs.
- 1Only pesticides permitted by the Pesticides Management Act, 2076 must be imported, produced, traded, or used.
- 2Buy pesticides only under the suggestion of agricultural technicians; store remaining pesticides safely.
- 3Labels of pesticides must be clear and intact.
- 4Do not store pesticides where children can reach them or near food storage.
- 5Store pesticides in an airtight container with no leakage.
- 6Read and strictly follow the instructions given on the label.
- 7Use only effective but less harmful pesticides; wear protective suits, masks, goggles, and gloves while using them.
- 8Clean spraying utensils immediately after use and store them safely — but not near water sources.
- 9Wash hands and take a bath immediately after spraying pesticides.
- 10Follow integrated pest management methods as far as possible.
- 11Do not sell or consume vegetables, fruits, and crops immediately after using pesticides.
- 12The most dangerous (Group IB) pesticides must be bought only under the direction of a crop protection officer.
- 13Remember: all pesticides are poisons, they are not medicines.
5. Chemical Pollution
Environmental pollution causes trouble for humans and all living beings in their survival. It degrades the quality of environmental components like air, water, and soil, causing imbalance in the ecosystem.
Chemical pollution: foamy, discoloured wastewater from industrial and chemical discharge flowing into a stream.
Pollution causes negative impacts such as airborne disease transmission (air pollution) and waterborne disease transmission (water pollution). Increasing carbon dioxide from air pollution also raises the average temperature of the earth.
Different pesticides used to kill insects, pests, and rodents contain poison and kill useful insects along with harmful ones, creating imbalance in the ecosystem. DDT (Dichlorodiphenyltrichloroethane) causes physical and biological environmental pollution.
- Polluted water negatively affects aquatic and terrestrial animals, including their reproductive systems.
- It causes different respiratory diseases.
- Reproductive capacity and growth of fish and birds are affected — birds lay fewer eggs, some are infertile, and some fertile eggs fail to hatch due to thin, fragile shells.
- Pesticides like BHC (benzene hexachloride), methoxychloride, aldrin, and dieldrin cause similar effects.
Health effects of pesticide exposure: skin irritation/blisters on hands and a diagram comparing a normal lung with an asthmatic lung.
Insecticides and chemical fertilizers reach water sources through rainwater and affect ecosystems there, destroying aquatic animals. Chemicals like insecticides, fungicides, and weedicides pollute soil, and substances like DDT, aldrin, dieldrin, and parathion degrade soil quality.
SEE Focus: Aldrin, Dieldrin, DDT, BHC, Chlordane, Lindane, and Endosulfan are all banned in Nepal. Production, buying, selling, export, and import of Dichlorvos insecticide is restricted in Nepal.
The haphazard use and disposal of industrial chemicals like cement, ceramics, glass, plastic, fiber, chemical fertilizers, soap, and detergent has degraded environmental quality and caused ecosystem imbalance. They should not be disposed of directly into water sources or agricultural land.
Measures for Proper Management of Industrial Chemicals
- Glass, ceramics, plastic, and fiber pieces should not be thrown haphazardly; manage them in proper places.
- Cement sacks should be tied and covered properly to prevent dust from blowing.
- Use organic/compost fertilizer instead of chemical fertilizers where possible.
- Use chemical fertilizers and pesticides only as suggested by agriculture experts.
- Waste water after using soap and detergent should not be mixed directly into water sources or farmland — collect it separately.
Common Mistakes in SEE
- Do not confuse first class preservatives (natural, e.g. salt, sugar, vinegar) with second class preservatives (chemically derived, e.g. sodium benzoate).
- Remember pesticides are classified in three different ways: by effect on environment, by pest affected, and by mode of action — do not mix these classifications.
- Soap is biodegradable; detergent is non-biodegradable — this is a common 'give reason' question.
- Detergent is called 'soapless soap' because it works like soap but has a different chemical composition and works even in hard water.
- DDT, Aldrin, Dieldrin, BHC, Chlordane, Lindane, and Endosulfan are banned pesticides in Nepal — remember this list for SEE.
Quick Revision
- Food preservatives = substances that stop food from decaying; 3 types: chemical, natural, and ripening-inducing.
- First class preservatives = natural (salt, sugar, honey); second class = chemically derived (sodium benzoate, nitrates), used in limited amount only.
- Ripening agents (calcium carbide, ethylene gas, ethephon) speed up fruit ripening but can harm health if overused.
- Natural cleansers: Reetha (soapberry, saponin), Peena (mustard cake), wood ash, Sajiban, lemon juice.
- Soap = sodium/potassium salt of fatty acid, made by saponification, biodegradable.
- Detergent = soapless soap, made from hydrocarbons, works in hard water, non-biodegradable.
- Pesticide = poison used to kill/control harmful pests; classified by environmental effect, pest type, and mode of action.
- DDT first used in Nepal in 1952 AD for malaria control; many organochlorine pesticides are now banned in Nepal.
- Chemical pollution degrades air, water, and soil quality and disturbs the ecosystem.